139005-44-0

Basic information

• Product Name: Acetic acid, [[2-(acetyloxy)cyclohexyl]thio]-, ethyl ester, trans-
• CAS NO: 139005-44-0
• Molecular Formula: C12H20O4S
• Molecular Weight: 260.354
• Mol File: 139005-44-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid, [[2-(acetyloxy)cyclohexyl]thio]-, ethyl ester, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [[2-(acetyloxy)cyclohexyl]thio]-, ethyl ester, trans-(139005-44-0)
• EPA Substance Registry System: Acetic acid, [[2-(acetyloxy)cyclohexyl]thio]-, ethyl ester, trans-(139005-44-0)

Safety Data

• Hazardous Substances Data: 139005-44-0(Hazardous Substances Data)

Upstream product

• 139005-41-7 2-<(carboethoxy)methylthio>cyclohexanone 
• 109314-65-0 1-nitrocyclohexene oxide 
• 2562-37-0 1-nitrocyclohexene 
• 108-24-7 acetic anhydride 
• 82622-17-1 trans-2-hydroxycyclohexyl(carboethoxy)methyl sulfide 

Relevant articles and documents

CHEMISTRY OF α-NITROEPOXIDES: SYNTHESIS OF USEFUL INTERMEDIATES VIA NUCLEOPHILIC RING OPENING OF α-NITROEPOXIDES

Various α-nitroepoxides are converted into corresponding 1,2-diketones via two different ways of ring opening viz. with Pd(O) and with DMSO/BF3*EtO2 (or ClSiMe3).In addition to this, a variety of nucleophiles are reacted with α-nitrocyclopentene oxide 6 and α-nitrocyclohexene oxide 7 to form the corresponding α-substituted ketones which are useful intermediates in organic synthesis.Two of the products so obtained viz. 32 and 33 are also transformed further into optically active thialactones 38 and 39 respectively via baker's yeast reduction followed by lactonisation.