1390641-82-3Relevant articles and documents
Tetrahedral Tetrakis(p-ethynylphenyl) Group IV Compounds in Microporous Polymers: Effect of Tetrel on Porosity
Uptmoor, Andrea C.,Geyer, Florian L.,Rominger, Frank,Freudenberg, Jan,Bunz, Uwe H. F.
, p. 448 - 454 (2018)
Three Sonogashira–Hagihara polymerization protocols were applied for the synthesis of conjugated microporous polymers (CMPs) by using group IV tetra(p-ethynylphenyl) monomers with 1,4-diiodobenzene or 1,4-dibromobenzene. The optical properties and surface areas of the CMPs were compared and related to the preparation conditions and the geometry of the tetrahedral building block as obtained after X-ray analysis. In each series, surface areas decreased—independently from the chosen parameters of catalyst, base, and solvent—from carbon-centered CMPs (1595 m2 g?1) to silicon-, germanium-, and tin-centered (649 m2 g?1) networks.