1391932-43-6

Basic information

• Product Name: 4-(benzyloxy)-8-bromoquinoline
• Synonyms: 4-(benzyloxy)-8-bromoquinoline
• CAS NO: 1391932-43-6
• Molecular Weight: 314.181
• Mol File: 1391932-43-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 4-(benzyloxy)-8-bromoquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(benzyloxy)-8-bromoquinoline(1391932-43-6)
• EPA Substance Registry System: 4-(benzyloxy)-8-bromoquinoline(1391932-43-6)

Safety Data

• Hazardous Substances Data: 1391932-43-6(Hazardous Substances Data)

Upstream product

• 57798-00-2 4-hydroxy-8-bromoquinoline 
• 100-39-0 benzyl bromide 
• 57798-00-2 8-bromo-1,4-dihydroquinolin-4-one 
• 100-46-9 benzylamine 

Downstream Products

• 1391932-40-3 (E)-N-((4-(benzyloxy)quinolin-8-yl)methylene)aniline 
• 1391932-44-7 4-(benzyloxy)quinoline-8-carbaldehyde 
• 57798-00-2 4-hydroxy-8-bromoquinoline 

Relevant articles and documents

Photoreductive Removal of O-Benzyl Groups from Oxyarene N-Heterocycles Assisted by O-Pyridine-pyridone Tautomerism

Facile photoreductive protocols have been developed to remove benzyl O-protective groups from oxyarene N-heterocycles at positions capable for 2-/4-O-pyridine-2-/4-pyridone tautomerism. Blue light irradiation, a [Ru] or [Ir] photocatalyst, and ascorbic acid in a water-acetonitrile solution debenzylates a variety of aryl N-heterocycles cleanly and selectively. Ascorbic acid has two functions in the reaction. On the one hand, it protonates the N-heterocycles that reduces their reduction potentials notably and on the other hand it acts as a sacrificial reductant. Reduction potentials and free energy barriers calculated at the CPCM-B3LYP/6-31+G? level can predict the reactivities of the studied substrates.