139229-57-5

Basic information

• Product Name: ethyl 1-(trifluoroMethyl)cyclopropanecarboxylate
• Synonyms: ethyl 1-(trifluoroMethyl)cyclopropanecarboxylate;Cyclopropanecarboxylic acid, 1-(trifluoroMethyl)-, ethyl ester;1-(Trifluoromethyl)cyclopropanecarboxylic acid ethyl ester;ethyl 1-(trifluoromethyl)cyclopropane-1-carboxylate
• CAS NO: 139229-57-5
• Molecular Formula: C₇H₉F₃O₂
• Molecular Weight: 182.1403696
• Mol File: 139229-57-5.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 127.4±35.0 °C(Predicted)
• Appearance: /
• Density: 1.311±0.06 g/cm3(Predicted)
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: ethyl 1-(trifluoroMethyl)cyclopropanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 1-(trifluoroMethyl)cyclopropanecarboxylate(139229-57-5)
• EPA Substance Registry System: ethyl 1-(trifluoroMethyl)cyclopropanecarboxylate(139229-57-5)

Safety Data

• Hazardous Substances Data: 139229-57-5(Hazardous Substances Data)

Usage

Description

Ethyl 1-(trifluoroMethyl)cyclopropanecarboxylate is an organic compound that features a cyclopropane ring with a trifluoromethyl group and an ester functional group derived from ethyl alcohol. It is known for its unique chemical properties and potential applications in various industries.

Uses

Used in Agricultural Industry:
Ethyl 1-(trifluoroMethyl)cyclopropanecarboxylate is used as an intermediate chemical for the synthesis of fungicidal and pesticidal benzyl cyclopropanecarboxylates. These compounds are effective in controlling and preventing fungal and pest infestations in crops, thereby contributing to increased agricultural productivity and crop protection.

Upstream product

• 3697-66-3 1,1-cyclopropanedicarboxylic acid monoethyl ester 
• 7440-47-3 chromium 
• 7440-02-0 nickel 
• 7439-98-7 molybdenum 
• 1559-02-0 diethyl cyclopropane-1,1-dicarboxylate 

Downstream Products

• 1267852-26-5 2-(4-(6-aminopyridin-3-yl)-2-fluorophenyl)-N-(5-(1-(trifluoromethyl)cyclopropyl)isoxazol-3-yl)acetamide 

Relevant articles and documents

Deoxofluorination of Aliphatic Carboxylic Acids: A Route to Trifluoromethyl-Substituted Derivatives

A practical method for the synthesis of functionalized aliphatic trifluoromethyl-substituted derivatives from aliphatic acids is developed. The transformation proceeds with sulfur tetrafluoride in the presence of water as a key additive. Compared to previous methods, the reaction gives products with full retention of stereo- and absolute configuration of chiral centers.

Ortho-substituted benzyl esters of cyclopropanecarboxylic acids

Ortho-substituted benzyl esters of cyclopropanecarboxylic acids I STR1 where X is N or CH and A is one of the following cyclopropane radicals: STR2 where R1 is CN, C2 -C8 -alkyl, CF3, C3 -C8 -alkenyl, (C1 -C4 -alkoxycarbonyl, unsubstituted or substituted phenyl-C1 -C6 -alkyl or phenyl-C3 -C6 -alkenyl, ethoxyphenyl, 2- or 3-bromophenyl, 2- or 4-trifluoromethylphenyl, 2,4- or 2,6-difluorophenyl, 2-fluoro-6-chlorophenyl, 2,4- or 2,6-dimethylphenyl, 2,3,6-trichlorophenyl or trimethylsilyl, R2 is H or halogen, R3 is unsubstituted or substituted phenyl, R4 is CH3 or halogen and Hal is halogen, with the proviso that X is CH when R1 is CF3 or trimethylsilyl, are suitable as fungicides and for controlling pests.