1393642-86-8

Basic information

• Product Name: methyl (Z)-2-(benzyloxy)-3-(tert-butyldimethylsilyloxy)-4-phenylbut-3-enoate
• CAS NO: 1393642-86-8
• Molecular Weight: 412.601
• Mol File: 1393642-86-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (Z)-2-(benzyloxy)-3-(tert-butyldimethylsilyloxy)-4-phenylbut-3-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-2-(benzyloxy)-3-(tert-butyldimethylsilyloxy)-4-phenylbut-3-enoate(1393642-86-8)
• EPA Substance Registry System: methyl (Z)-2-(benzyloxy)-3-(tert-butyldimethylsilyloxy)-4-phenylbut-3-enoate(1393642-86-8)

Safety Data

• Hazardous Substances Data: 1393642-86-8(Hazardous Substances Data)

Upstream product

• 104620-33-9 methyl 2-diazo-3-oxo-4-phenylbutanoate 
• 1380412-85-0 methyl (Z)-3-(tert-butyldimethylsilyloxy)-2-diazo-4-phenylbut-3-enoate 
• 100-51-6 benzyl alcohol 

Relevant articles and documents

Rhodium(II)- and copper(II)-catalyzed reactions of enol diazoacetates with nitrones: Metal carbene versus lewis acid directed pathways

A complimentary cat.: Copper(II) hexafluoroantimonate catalyzes the formal [3+3] cycloaddition of Lewis acid activated nitrones and vinyl diazoacetates to produce 3,6-dihydro-1,2-oxazines in yields of up to 96 % and diastereoselectivities greater than 25:1 (see scheme). This process compliments the metal carbene pathway that is catalyzed by rhodium(II) species. Copyright