1393726-59-4

Basic information

• Product Name: (H-2,6-(C₆H₃Bu^t)₂pyridine)AuMe(CF₃CO₂)
• CAS NO: 1393726-59-4
• Molecular Weight: 667.521
• Mol File: 1393726-59-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (H-2,6-(C₆H₃Bu^t)₂pyridine)AuMe(CF₃CO₂)(CAS DataBase Reference)
• NIST Chemistry Reference: (H-2,6-(C₆H₃Bu^t)₂pyridine)AuMe(CF₃CO₂)(1393726-59-4)
• EPA Substance Registry System: (H-2,6-(C₆H₃Bu^t)₂pyridine)AuMe(CF₃CO₂)(1393726-59-4)

Safety Data

• Hazardous Substances Data: 1393726-59-4(Hazardous Substances Data)

Upstream product

• 1384526-43-5 (2,6-(C₆H₃Bu^t)₂pyridine)Au(CF₃CO₂) 
• 1393726-58-3 (2,6-(C₆H₃Bu^t)₂pyridine)AuMe 
• 76-05-1 trifluoroacetic acid 

Relevant articles and documents

Selective Au-C cleavage in (C∧N∧C)Au(III) aryl and alkyl pincer complexes

Treatment of gold(III) pincer complexes (C∧N ∧C)*AuX with trifluoroacetic acid (X = C6F 5, thiophenyl, Me, Et) or of (C∧N∧C) *AuOAcF with AgOAcF/arylboronic acids leads to the selective cleavage of a C-Au bond under mild conditions to give the bidentate complexes (HC-C∧N)*Au(X)(OAcF) [(C ∧N∧C)* = 2,6-(C6H 3But)2pyridine]. Alkylation of (C ∧N∧C)*Au(OAcF) with AlR 3 (R = Me, Et) proved to be a high-yielding route to gold(III) alkyls. Au-C cleavage significantly influences reactivity, e.g., with boronic acids. The photoemission of the cleavage product (HC-C∧N) *Au(C6H4F)(OAcF) is about an order of magnitude more intense than that of its tridentate parent compound.