1394016-63-7Relevant articles and documents
Coordination-driven synthesis of Ag(I) compounds based on a double emission ligand consisting of 1,3,4-oxadiazole and cyclotriphosphazene units
Wu, Xiang-Wen,Wang, Xiao-Yan,Li, Qing-Long,Ma, Jian-Ping,Dong, Yu-Bin
, p. 3299 - 3307 (2012)
A new ligand (L) which consists of cyclotriphosphazene and 1,3,4-oxadiazole units is reported. Two new Ag(I) coordination compounds {[Ag(L)SO 3CF3] n (1) and Ag2L 2(NO3)2 (2)} based on L and Ag(I) salts are obtained. Compound 1 features a 1-D chain, in which the ligand L adopts a divergent trans-conformation, whereas 2 is a discrete binuclear Ag(I) molecule in which L adopts convergent cis-conformation. Compounds 1 and 2 are fully characterized by 1H-NMR, Infrared, elemental analysis, X-ray powder, and single-crystal diffraction. Luminescent properties of 1 and 2 are investigated.