1394313-89-3

Basic information

• Product Name: 6-phenylhex-5-yne-1,4-diol
• Synonyms: 6-phenylhex-5-yne-1,4-diol
• CAS NO: 1394313-89-3
• Molecular Weight: 190.242
• Mol File: 1394313-89-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 6-phenylhex-5-yne-1,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 6-phenylhex-5-yne-1,4-diol(1394313-89-3)
• EPA Substance Registry System: 6-phenylhex-5-yne-1,4-diol(1394313-89-3)

Safety Data

• Hazardous Substances Data: 1394313-89-3(Hazardous Substances Data)

Upstream product

• 5371-52-8 2-hydroxytetrahydrofuran 
• 536-74-3 phenylacetylene 
• 138695-86-0 6-(tert-Butyl-diphenyl-silanyloxy)-1-phenyl-hex-1-yn-3-ol 

Downstream Products

• 120749-62-4 2-(2-phenylethylnyl)-tetrahydrofuran 
• 1361320-60-6 C₁₃H₁₂O₃ 
• 18138-77-7 (E)-2-styryltetrahydrofuran 
• 59700-95-7 (E)-6-phenylhex-5-ene-1,4-diol 
• 59137-68-7 1-phenyl-2-(tetrahydrofuran-2-yl)ethan-1-one 

Relevant articles and documents

Stereoselective organocatalytic oxidation of alcohols to enals: A homologation method to prepare polyenes

A novel method for organocatalytic oxidation through oxidative enamine catalysis was developed with excellent compatibility for the direct syntheses of enals from simple saturated alcohols. By using this amine-catalyzed IBX-oxidation, a wide range of aromatic and aliphatic substituted enals were successfully generated in high yields and exclusively stereoselective E-geometry. Moreover, varying the solvents and/or the loading amounts of IBX allowed for the selective oxidation of alcohols and aldehydes. Importantly, the homologous application of this method provided a selective and efficient way of preparing various highly sensitive conjugated polyene frameworks, which are enriched in natural products.

Palladium-catalyzed asymmetric synthesis of 2-alkynyl oxacycles

Oxyacetylene: Unusual palladium-catalyzed cyclizations of cyclic and acyclic propargylic carbonates give 2-alkynyl oxacycles. The reactions proceed with very high stereoselectivity for both syn- and anti-disubstituted furans and pyrans, and with exceptional regioselectivity. In addition, two-directional cyclizations of bis-propargylic carbonate substrates yield bifurans with complete stereocontrol for all diastereomers.