1394369-76-6

Basic information

• Product Name: [manganes(III)(3-(2-hydroxyphenyl)-5-phenyl-pyrazole(-H))2(azide)]
• CAS NO: 1394369-76-6
• Molecular Weight: 567.488
• Mol File: 1394369-76-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [manganes(III)(3-(2-hydroxyphenyl)-5-phenyl-pyrazole(-H))2(azide)](CAS DataBase Reference)
• NIST Chemistry Reference: [manganes(III)(3-(2-hydroxyphenyl)-5-phenyl-pyrazole(-H))2(azide)](1394369-76-6)
• EPA Substance Registry System: [manganes(III)(3-(2-hydroxyphenyl)-5-phenyl-pyrazole(-H))2(azide)](1394369-76-6)

Safety Data

• Hazardous Substances Data: 1394369-76-6(Hazardous Substances Data)

Upstream product

• 19726-12-6 3-(2-hydroxyphenyl)-5-phenyl-pyrazole 

Relevant articles and documents

Mononuclear and dinuclear manganese compounds stabilized by supramolecular interactions

New manganese compounds [Mn(HphpzMe)2(H2phpzMe) (HCO2)] (1), [Mn2(phpzMe)2(HphpzMe) 2(OCH3)]·2CH3OH (2), Na{[Mn(HphpzPh)(phpzPh)(MeOH)2]2}(HCO2) (3), [Mn(HphpzPh)2(EtOH)2]ClO4·2EtOH (4) and [Mn(HphpzPh)2N3] (5) were synthesized and characterized with various techniques. 1, 4 and 5 are mononuclear manganese(iii) compounds, 2 is a mixed-valence dinuclear manganese(iii/iv) compound, and 3 is a trinuclear compound containing two manganese(iii) ions and a sodium(i) ion. A remarkable feature is the spontaneous formation of the formate ion as a result of the methanol or methoxide oxidation in compounds 1 and 3. Using ethanol precludes the formation of the formate and compound 4 is obtained. The molecular structure of all compounds is stabilized by supramolecular interactions, including strong hydrogen bonding and π-π interactions.