139564-98-0Relevant articles and documents
Studies on the Chemistry of O,N- and S,N-Containing Heterocycles, 13. - Investigations on the Ring Contraction of 1,5-Benzothiazepines to 1,4-Benzothiazines
Erker, Thomas,Bartsch, Herbert
, p. 403 - 406 (2007/10/02)
Reaction of the (3R)-1,5-benzothiazepinon derivative 5 with NaNO2 in glacial acetic acid leads to the rac-1,4-benzothiazinone derivatives 6a and 7.Furthermore, reaction of 5 with NaNO2 in sulphuric acid/KBr yields the ring-contracted compound rac-6b.Compo