139592-95-3

Basic information

• Product Name: 2H-Isoindole-4,7-dione, 2-methyl-5-(phenylthio)-
• CAS NO: 139592-95-3
• Molecular Formula: C15H11NO2S
• Molecular Weight: 269.324
• Mol File: 139592-95-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2H-Isoindole-4,7-dione, 2-methyl-5-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Isoindole-4,7-dione, 2-methyl-5-(phenylthio)-(139592-95-3)
• EPA Substance Registry System: 2H-Isoindole-4,7-dione, 2-methyl-5-(phenylthio)-(139592-95-3)

Safety Data

• Hazardous Substances Data: 139592-95-3(Hazardous Substances Data)

Upstream product

• 107-97-1 sarcosine 
• 18232-03-6 2-phenylsulfanyl-[1,4]benzoquinone 

Relevant articles and documents

Synthesis and Polarographic Behavior of 2H-Isoindole-4,7-diones

2-Phenylthio-1,4-benzoquinone (1a) reacts with azomethine ylide AY-A to give 2-methyl-5-phenylthio-2H-isoindole-4,7-dione (4f).With 2-(N-methylanilino)-5-methyl-1,4-benzoquinone (1b), the azomethine ylide AY-B undergoes cycloaddition to yield an inseparable mixture of 5a-methyl-8-(N-methylanilino)-2,3,5,5a,9a,9b-hexahydro-pyrrolo-1H-isoindole-6,9-dione (5 bI) and 9a-methyl-7-(N-methylanilino)-2,3,5,5a,9a,9b-hexahydropyrrolo-1H-isoindole-6,9-dione (5 bII).The structures of 5 bI and 5 bII were established on basis of two-dimensional-NMR-techniques.The mechanism of the cycloaddition of azomethine ylides to 1,4-quinones was studied on basis of cyclovoltammetric investigations.To determine the electron affinity of the isoindoledione derivatives 4 a-f and 5 a-b the peak potentials were measured by differential pulse polarography (DPP). Keywords. 1,3-Dipolar cycloaddition; Isoindoledione derivatives; 2 D-NMR; Cyclovoltammetry; DPP.