139608-41-6

Basic information

• Product Name: 1-Propanone, 2-[2-hydroxy-3-phenyl-2-(phenylmethyl)propoxy]-1-phenyl-
• CAS NO: 139608-41-6
• Molecular Formula: C25H26O3
• Molecular Weight: 374.48
• Mol File: 139608-41-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 2-[2-hydroxy-3-phenyl-2-(phenylmethyl)propoxy]-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 2-[2-hydroxy-3-phenyl-2-(phenylmethyl)propoxy]-1-phenyl-(139608-41-6)
• EPA Substance Registry System: 1-Propanone, 2-[2-hydroxy-3-phenyl-2-(phenylmethyl)propoxy]-1-phenyl-(139608-41-6)

Safety Data

• Hazardous Substances Data: 139608-41-6(Hazardous Substances Data)

Upstream product

• 40814-69-5 3,3-bis(phenylmethyl)-1,2-dioxetane 
• 30085-70-2 [E]-1-morpholino-1-phenyl-1-propene 

Relevant articles and documents

α-Alkoxy Ketones from the Nucleophilic Substitution on the Peroxide Bond of 3,3-Disubstituted 1,2-Dioxetanes by Enamines

The reaction of 1,2-dioxetanes with enamines as ?-nucleophiles was investigated. 3,3-Dibenzyl-1,2-dioxetane (1) was allowed to react with enamines 2a-c in methylene chloride to afford after hydrolysis the corresponding α-alkoxylated ketones 4a-c.Additionally, the reaction of the dimedone-derived enamine 3 with dioxetane 1 yielded the oxidized enamine adduct 5.Nucleophilic attack of the enamine β-carbon (SN2 reactivity) on the sterically less hindered site of the dioxetane peroxide bond is proposed to constitute the initial step of the reaction.