13964-88-0

Basic information

• Product Name: Bis(cobalt tetracarbonyl)mercury
• CAS NO: 13964-88-0
• Molecular Weight: 542.66
• Mol File: 13964-88-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Bis(cobalt tetracarbonyl)mercury(CAS DataBase Reference)
• NIST Chemistry Reference: Bis(cobalt tetracarbonyl)mercury(13964-88-0)
• EPA Substance Registry System: Bis(cobalt tetracarbonyl)mercury(13964-88-0)

Safety Data

• Hazardous Substances Data: 13964-88-0(Hazardous Substances Data)

Upstream product

• 69480-70-2 tetracarbonyldigermanylcobalt 
• 201230-82-2 carbon monoxide 
• 15906-57-7 (CO)4CoHgCo(CO)3P(C₆H₅)3 
• 18115-12-3 ClHgCo(CO)4 
• 4149-28-4 bis(triethylgermyl)mercury 
• 57064-39-8 (CO)4CoHgCo(CO)2(C₆H₅)2PCH₂CH₂P(C₆H₅)2 
• 16986-00-8 {CdCo₂(CO)8} 
• 15226-74-1 dicobalt octacarbonyl 

Downstream Products

• 593-95-3 carbonyl dibromide 
• 37336-89-3 (C₆H₅)3PCH₂(C₆H₅)⁽¹⁺⁾*ClHg(Co(CO)4)2^(1-)=((C₆H₅)3PCH₂(C₆H₅))(ClHg(Co(CO)4)2) 
• 14515-69-6 diphenylacetylene hexacarbonyl dicobalt 
• 18116-81-9 Hg(Co(CO)3C₈H₈P(C₆H₅))2 
• 12155-88-3 [(Co₂(CO)6)(PhC_.tplbond.CC_.tplbond.CPh)] 
• 34825-38-2 Hg(Co(CO)2(P(O(C₆H₅))(OCH₂)2)2)2 
• 97768-66-6 Co₂(CO)6C₂(C₆H₅)COOCH₃ 
• 20243-34-9 Hg(Co(CO)3P(C₆H₅)3)2 
• 119726-26-0 C₄H₄Co(CO)P(C₆H₅)3HgCo(CO)4 
• 34825-43-9 Hg(Co(CO)2(P(CH₃)2(C₆H₅))2)2 
• 14881-95-9 trimethylsilylphenylacetylene dicobalt hexacarbonyl 
• 34825-41-7 Hg(Co(CO)2(P(C₆H₅)(OCH₃)2)2)2 
• 34952-36-8 Hg(Co(CO)2(P(CH₃)(C₆H₅)2)2)2*C₆H₆ 
• 34825-42-8 Hg(Co(CO)2(P(C₆H₅)2OCH₃)2)2 

Relevant articles and documents

Studies in the chemistry of bonds between metals. I. The synthesis of transition metal carbonyl derivatives of zinc and cadmium by a metal-exchange reaction

The metal-exchange reactions of a number of transition metal carbonyl derivatives of mercury of the m2Hg type (m = Co(CO)4, Fe(CO)2C5H5, Cr(CO)3C5H5, Mo(CO)3C5H5, and W(CO)3C5H5) and the mixed-metal compound C5H5Fe(CO)2HgCo(CO)4 with zinc and cadmium have been shown to be convenient synthetic routes to the novel zinc and cadmium analogs, m2Zn and m2Cd, and C5H5Fe(CO)2ZnCo(CO)4. A polar solvent such as THF was required to promote the exchange in the case of the molybednum and tungsten derivatives. The conversion of Hg[Mn(CO)5]2 to Zn[Mn(CO)5]2 occurred in diglyme at 120°. The similarity of the infrared spectra of the new zinc and cadmium compounds with those of the well-studied mercury analogs indicated that all of the compounds contain linear arrangements of covalently bonded metal atoms. Comparison of the Mo?ssbauer parameters with the infrared data for the M[Fe(CO)2C5H5]2 series (M = Zn, Cd, Hg) suggested that both σ and π bonding are important in the metal-metal interactions. Mass spectra, reported for the M[Co(CO)4]2 and M[Cr(CO)3C5H5]2 series, gave a qualitative indication that the metal-metal bond strengths decrease in the order Zn > Cd > Hg. Detailed preparations for the mercury derivatives are described in the Experimental Section.