139684-64-3

Basic information

• Product Name: (Z)-prop-1'-enyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside
• Synonyms: (Z)-prop-1'-enyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside
• CAS NO: 139684-64-3
• Molecular Weight: 580.721
• Mol File: 139684-64-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-prop-1'-enyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-prop-1'-enyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside(139684-64-3)
• EPA Substance Registry System: (Z)-prop-1'-enyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside(139684-64-3)

Safety Data

• Hazardous Substances Data: 139684-64-3(Hazardous Substances Data)

Upstream product

• 6207-45-0 2-allyloxy-3,4,5-tris-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran 
• 178319-02-3 allyl 2,6-di-O-benzyl-3-O-p-methoxybenzyl-α-D-galactopyranoside 
• 178319-05-6 allyl 2,6-di-O-benzyl-3-O-p-methoxybenzyl-α-D-glucopyranoside 
• 178319-10-3 Benzoic acid (2R,3R,4S,5R,6S)-6-allyloxy-5-benzyloxy-2-benzyloxymethyl-4-(4-methoxy-benzyloxy)-tetrahydro-pyran-3-yl ester 
• 178319-04-5 allyl 2,6-di-O-benzyl-3-O-p-methoxybenzyl-4-O-methylsulfonyl-α-D-galactopyranoside 
• 169822-03-1 allyl 2,6-di-O-benzyl-α-D-glucopyranoside 
• 37111-91-4 allyl 2,6-di-O-benzyl-α-D-galactopyranoside 

Downstream Products

• 58781-27-4 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside 
• 6564-72-3 2,3,4,6-tetra-O-benzyl-D-glucopyranose 
• 77117-44-3 methyl 2,3,6-tri-O-benzyl-4-O-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl)-α-D-glucopyranoside 
• 61474-61-1 methyl 2,3,4-tri-O-benzyl-6-O-(2,3,4,6-tetra-O-benzyl-D-glucopyranosyl)-α-D-glucopyranoside 

Relevant articles and documents

The allyl group for protection in carbohydrate chemistry. XXXI conversion of allyl 2,6-di-o-benzyl-α-d-galactopyranoside into allyl 2,6-di-o-benzyl-α-d-glucopyranoside and 2,6-di-o-benzyl-d-glucopyranose

Allyl 2,6-di-O-benzyl-α-D-galactopyranoside was converted by tin-mediated alkylation into the 3-O-p-methoxybenzyl ether which gave the 4-0-mesyl derivative. Sodium benzoate in refluxing N,N-dimethylformamide converted the last compound into allyl 4-O-benz