1399258-30-0Relevant articles and documents
Copper catalyst activation driven by photoinduced electron transfer: A prototype photolatent click catalyst
Harmand, Lydie,Cadet, Sarah,Kauffmann, Brice,Scarpantonio, Luca,Batat, Pinar,Jonusauskas, Gediminas,McClenaghan, Nathan D.,Lastecoueres, Dominique,Vincent, Jean-Marc
, p. 7137 - 7141 (2012)
PET cat. While the copper(II) tren ketoprofenate precatalyst 1 (see picture) is inactive at room temperature in methanol, it is quantitatively and rapidly reduced to its cuprous state upon light irradiation to provide a highly reactive click catalyst. By simply introducing air into the reaction medium the catalysis can be switched off and then switched on again by bubbling argon followed by irradiation. Copyright