139975-85-2

Basic information

• Product Name: 1H-Imidazole, 2-phenyl-1-[[2-(trimethylsilyl)ethoxy]methyl]-
• CAS NO: 139975-85-2
• Molecular Formula: C15H22N2OSi
• Molecular Weight: 274.438
• Mol File: 139975-85-2.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1H-Imidazole, 2-phenyl-1-[[2-(trimethylsilyl)ethoxy]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Imidazole, 2-phenyl-1-[[2-(trimethylsilyl)ethoxy]methyl]-(139975-85-2)
• EPA Substance Registry System: 1H-Imidazole, 2-phenyl-1-[[2-(trimethylsilyl)ethoxy]methyl]-(139975-85-2)

Safety Data

• Hazardous Substances Data: 139975-85-2(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 101226-33-9 1-((2-(trimethylsilyl)ethoxy)methyl)-1H-imidazole 
• 108-90-7 chlorobenzene 
• 76513-69-4 (2-trimethylethylsilylethoxy)methyl chloride 
• 670-96-2 2-Phenylimidazole 

Downstream Products

• 139975-89-6 2-phenyl-5-(trimethylsilyl)-1-<<2-(trimethylsilyl)ethoxy>methyl>-1H-imidazole 
• 1239332-14-9 2-phenyl-5-(3-(trifluoromethyl)phenyl)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-imidazole 
• 1239332-11-6 5-(3-methoxyphenyl)-2-phenyl-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-imidazole 
• 1239332-17-2 ethyl 3-(2-phenyl-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-imidazol-5-yl)benzoate 
• 157034-16-7 C₃₂H₂₈N₃O₂P 
• 139975-93-2 2-<5-(trimethylsilyl)-1-<<2-(trimethylsilyl)ethoxy>methyl>-1H-imidazol-2-yl>benzaldehyde 

Relevant articles and documents

Regioselective C-H alkenylation of imidazoles and its application to the synthesis of unsymmetrically substituted benzimidazoles

A palladium-catalyzed C-H alkenylation of imidazoles has been developed. High C5 selectivity was achieved for C2-unsubstituted and C2-substituted imidazoles using oxygen and copper(ii) acetate, respectively, as oxidants. The obtained products were applied

Catalytic C-H arylation of SEM-protected azoles with palladium complexes of NHCs and phosphines

The synthesis and catalytic evaluation of palladium complexes containing imidazolyl carbene ligand of varying steric and electronic properties is reported. These complexes catalyze the efficient C-H arylation of SEM-protected azole heteroarenes and thus provide a good method for preparation of a wide range of arylated free (NH)-azoles including pyrroles, indoles, imidazoles, and imidazo[1,2-a]pyridines. The reaction is operationally simple; the complexes are insensitive to moisture.

Heteroatom-Facilitated Ortho-Directed Lithiations of 2-Arylimidazoles

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