1401998-95-5Relevant articles and documents
Synthesis of γ-fluoroalkylated allylic amines derivatives via palladium-catalyzed Overman rearrangement
Jiang, Xin-Yi,Chu, Lingling,Wang, Ruo-Wen,Qing, Feng-Ling
, p. 6853 - 6857,5 (2012/12/12)
A Pd-catalyzed Overman rearrangement of α-fluoroalkylated allylic trichloroacetimidates has been developed. This reaction allows for an efficient synthesis of γ-fluoroalkylated allylic amine derivatives with excellent regio- and stereo-selectivities under
B -(3,3-Difluoroallyl)diisopinocampheylborane for the enantioselective fluoroallylboration of aldehydes
Ramachandran, P. Veeraraghavan,Tafelska-Kaczmarek, Agnieszka,Chatterjee, Anamitra
, p. 9329 - 9333,5 (2012/12/11)
The fluoroallylboration of aldehydes with B-(3,3-difluoroallyl) diisopinocampheylborane, which was prepared via the hydroboration of 1,1-difluoroallene, provides chiral 2,2-gem-difluorinated homoallylic alcohols in good yields and 91-97% ee.