1402704-26-0

Basic information

• Product Name: C₁₄H₁₃NO₃
• Synonyms: C₁₄H₁₃NO₃
• CAS NO: 1402704-26-0
• Molecular Weight: 243.262
• Mol File: 1402704-26-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₃NO₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₃NO₃(1402704-26-0)
• EPA Substance Registry System: C₁₄H₁₃NO₃(1402704-26-0)

Safety Data

• Hazardous Substances Data: 1402704-26-0(Hazardous Substances Data)

Upstream product

• 141091-37-4 2-(cyclohex-1-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 524-38-9 N-hydroxyphthalimide 
• 89490-05-1 cyclohex-1-enylboronic acid 

Downstream Products

• 1402704-75-9 C₁₄H₁₃NO₃ 
• 7472-23-3 2-benzoyloxycyclohexanone 

Relevant articles and documents

Synthesis of α-oxygenated ketones and substituted catechols via the rearrangement of N-enoxy- and N-aryloxyphthalimides

A common approach to the synthesis of α-oxygenated carbonyl compounds and catechols is the treatment of a carbonyl compound or a phenol with an electrophilic oxygen source. As an alternative approach to these important structures, formal [3,3]-rearrangements of N-enoxyphthalimides, N-enoxyisoindolinones, and N-aryloxyphthalimides have been explored. When used in combination with an initial Chan-Lam coupling, these transformations facilitate the dioxygenation of alkenylboronic acids for the synthesis of α-oxygenated ketones and the dioxygenation of arylboronic acids for the synthesis of catechols. The rearrangements of N-enoxyisoindolinones have also been shown to be diastereoselective.

Preparation of α-oxygenated ketones by the dioxygenation of alkenyl boronic acids

Two in two: Dioxygenation of alkenyl boronic acids has been achieved with N-hydroxyphthalimide. The two-step process involves etherification of an alkenyl boronic acid with N-hydroxyphthalimide followed by a [3,3] rearrangement. The dioxygenated product can then be hydrolyzed to form either the corresponding α-hydroxy ketone or the α-benzoyloxy ketone. Copyright