1403459-37-9Relevant articles and documents
Reactions of a Zn(i) complex with group 14 azides-formation of zinc azide and zinc hexazene complexes
Gondzik,Schulz,Blaeser,Woelper,Haack,Jansen
, p. 927 - 929 (2014)
Two zinc hexazene complexes L2Zn2(μ-1,6-R 2-N6) (L = HC[C(Me)N(2,4,6-Me3C 6H2)]2; R = Ph (3), Dipp = 2,6-i-Pr 2C6H3 (4)), were synthesized by reaction of the Zn(i) complex L2Zn2 (1) with phenyl azide and 2,6-diisopropylphenyl azide, respectively. 3 represents the second structurally characterized transition metal hexazene complex. In contrast, reactions of 1 with Me3MN3 (M = Si, Sn) yielded the azido complex [LZn(μ-N3)]2 (2) and Me3M-MMe3.