1403500-11-7

Basic information

• Product Name: 3-O-benzyl-6-deoxy-1,2-O-isopropylidene-5-p-methoxyphenylamino-5-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-α-D-xylofuranose
• Synonyms: 3-O-benzyl-6-deoxy-1,2-O-isopropylidene-5-p-methoxyphenylamino-5-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-α-D-xylofuranose
• CAS NO: 1403500-11-7
• Molecular Weight: 544.602
• Mol File: 1403500-11-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-O-benzyl-6-deoxy-1,2-O-isopropylidene-5-p-methoxyphenylamino-5-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-α-D-xylofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3-O-benzyl-6-deoxy-1,2-O-isopropylidene-5-p-methoxyphenylamino-5-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-α-D-xylofuranose(1403500-11-7)
• EPA Substance Registry System: 3-O-benzyl-6-deoxy-1,2-O-isopropylidene-5-p-methoxyphenylamino-5-(2,2-dimethyl-5-nitro-1,3-dioxan-5-yl)-α-D-xylofuranose(1403500-11-7)

Safety Data

• Hazardous Substances Data: 1403500-11-7(Hazardous Substances Data)

Upstream product

• 60766-57-6 2,2-dimethyl-5-bromo-5-nitro-1,3-dioxane 
• 547769-25-5 3-O-benzyl-5-deoxy-1,2-O-isopropylidene-5-[(4-methoxyphenyl)imino]-α-D-xylofuranose 

Relevant articles and documents

Preparation of sugar-derived 1,2-diamines via indium-catalyzed aza-Henry-type reaction: Application to the synthesis of 6-amino-1,6- dideoxynojirimycin

The combination of (p-methoxyphenyl)imine, a bromonitroalkane, and zinc in the presence of catalytic indium allows straightforward access to β-nitroamine derivatives. The use of chiral sugar-derived imines furnished the corresponding β-nitroamines in high yields and stereoselectivities, from which the corresponding 1,2-diamines were easily obtained. The synthetic utility of the sugar-derived 1,2-diamines in the preparation of iminosugars was illustrated in a concise synthesis of 6-amino-1,6-dideoxynojirimycin.