140421-17-6Relevant articles and documents
Conversion of Chiral Oxiranes into Chiral Aziridines with Retention of Configuration by Way of Chiral Episulfonium Ions and Reactions of the Aziridines with Grignard Reagents
Toshimitsu, Akio,Abe, Hideyuki,Hirosawa, Chitaru,Tamao, Kohei
, p. 3465 - 3472 (2007/10/02)
Chiral oxiranes are converted into chiral aziridines with overall retention of configuration by means of sulfur chemistry.The key step of this procedure is the transformation of the organosulfur intermediates, i.e., the replacement of a hydroxy group boun