140669-99-4

Basic information

• Product Name: Formamide, N-(2-chloropentyl)-N-(phenylmethyl)-
• CAS NO: 140669-99-4
• Molecular Formula: C13H18ClNO
• Molecular Weight: 239.745
• Mol File: 140669-99-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Formamide, N-(2-chloropentyl)-N-(phenylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Formamide, N-(2-chloropentyl)-N-(phenylmethyl)-(140669-99-4)
• EPA Substance Registry System: Formamide, N-(2-chloropentyl)-N-(phenylmethyl)-(140669-99-4)

Safety Data

• Hazardous Substances Data: 140669-99-4(Hazardous Substances Data)

Upstream product

• 6343-54-0 N-benzylformamide 
• 109-67-1 1-penten 
• 140669-90-5 N-benzyl-N-chloroformamide 

Relevant articles and documents

Photolytic and Chromium(II)-Promoted Addition Reactions of N-Halogenoformamides with Alkenes

Formamidyl radicals (HCONR) do not intramolecularly abstract hydrogen or cyclise onto aromatic rings, but do add intermolecularly to alkenes.The photolytic addition of N-halogenoformamides to alkenes is inhibited by N-alkylation.However, N-alkyl-N-halogenoformamides add to alkenes in the presence of chromium(II) species.The addition of N-halogenoformamides to alkenes occurs regiospecifically with formamidyl bonding to the less substituted terminus of the alkene.The adducts obtained from N-alkylformamidyls exist as mixtures of rotameric isomers whose configurations have been assigned.The reactivity of the formamidyl radical has been discussed in terms of its conformation and electron state.