140834-68-0

Basic information

• Product Name: Nonanoic acid, 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-methyl-, ethyl ester
• CAS NO: 140834-68-0
• Molecular Formula: C12H11F13O2
• Molecular Weight: 434.197
• Mol File: 140834-68-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Nonanoic acid, 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-methyl-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Nonanoic acid, 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-methyl-, ethyl ester(140834-68-0)
• EPA Substance Registry System: Nonanoic acid, 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluoro-2-methyl-, ethyl ester(140834-68-0)

Safety Data

• Hazardous Substances Data: 140834-68-0(Hazardous Substances Data)

Upstream product

• 355-43-1 n-perfluorohexyl iodide 
• 97-63-2 methyl methacrylate 
• 335-56-8 1-bromo-1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane 

Relevant articles and documents

Cobaloxime-Catalyzed Hydroperfluoroalkylation of Electron-Deficient Alkenes with Perfluoroalkyl Halides: Reaction and Mechanism

Direct hydroperfluoralkylation of electron-deficient alkenes - ethyl acrylates 4, 7, and 8, acrylonitrile (5), and methyl vinyl ketone (6) - with perfluoroalkyl halides RfX (1, X = I; 2, X = Br) in the presence of cobaloxime(III) (3) and zinc gives 1:1 hydroperfluoroalkylation adducts in good yields.This reaction provides a convenient synthesis of β-(perfluoroalkyl)carboxylic esters 9, 12, and 13, nitriles 10, and ketones 11.Details of the reaction including effect of solvent, temperature, and ratio of reagents were examined.The reaction is proposed to proceed via a radical mechanism initiated by low-valent cobalt.