14100-81-3

Basic information

• Product Name: cis 4H-1-trifluoromethyl/-decafluorocyclohexane
• Synonyms: cis 4H-1-trifluoromethyl/-decafluorocyclohexane
• CAS NO: 14100-81-3
• Molecular Weight: 332.064
• Mol File: 14100-81-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis 4H-1-trifluoromethyl/-decafluorocyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: cis 4H-1-trifluoromethyl/-decafluorocyclohexane(14100-81-3)
• EPA Substance Registry System: cis 4H-1-trifluoromethyl/-decafluorocyclohexane(14100-81-3)

Safety Data

• Hazardous Substances Data: 14100-81-3(Hazardous Substances Data)

Upstream product

• 16825-99-3 4-H-decafluoro-1-methyl-1,4-cyclohexadiene 
• 291-64-5 cycloheptane 
• 98-08-8 α,α,α-trifluorotoluene 
• 374-74-3 1-chloro-decafluoro-4-trifluoromethyl-cyclohexane 

Downstream Products

• 374-79-8 4-trifluoromethylnonafluorocyclohex-1-ene 
• 432-16-6 1-trifluoro-methylnonafluorocyclohex-1-ene 

Relevant articles and documents

POLYFLUORO-COMPOUNDS BASED ON THE CYCLOHEPTANE RING SYSTEM. PART 1. COMPOUNDS DERIVED FROM TRIDECAFLUOROCYCLOHEPTANE

Partial fluorination of cycloheptane by cobaltic fluoride gave a mixture of polyfluorides, of which tridecafluorocycloheptane was present in significant proportions.With aqueous alkali this afforded dodecafluorocycloheptene, which with lithium aluminium hydride gave 1H-undecafluorocyclohept-1-ene.Each of these cyclo-olefins was oxidised to decafluoropimelic acid.Methanol/KOH reacted with dodecafluorocycloheptene to give mainly 1-methoxy-undecafluorocyclohept-1-ene together with ca 15percent of the 3-methoxy-isomer, and some 1,2-dimethoxydecafluorocyclohept-1-ene.The 1-methoxy-1-ene and cobaltic fluoride gave 1-methoxy- and 1-fluoromethoxytridecafluorocycloheptanone: the former was demethylated by sulphuric acid to dodecafluorocycloheptanone.The dichloro-adduct of the perfluoro-olefin was reduced by lithium aluminium hydride to a complex mixture, from which 1H/2H- and 1H,2H-dodecafluorocycloheptane were isolated.