1410247-90-3

Basic information

• Product Name: [HC(CMeN(2,6-iPr₂C₆H₃))2AlHO]2SiPh₂
• CAS NO: 1410247-90-3
• Molecular Weight: 1105.59
• Mol File: 1410247-90-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [HC(CMeN(2,6-iPr₂C₆H₃))2AlHO]2SiPh₂(CAS DataBase Reference)
• NIST Chemistry Reference: [HC(CMeN(2,6-iPr₂C₆H₃))2AlHO]2SiPh₂(1410247-90-3)
• EPA Substance Registry System: [HC(CMeN(2,6-iPr₂C₆H₃))2AlHO]2SiPh₂(1410247-90-3)

Safety Data

• Hazardous Substances Data: 1410247-90-3(Hazardous Substances Data)

Upstream product

• 278608-73-4 [(HC(CMeN(2,6-i-Pr₂C₆H₃))2)AlH₂] 
• 947-42-2 diphenylsilanediol 

Relevant articles and documents

Synthesis and characterization of compounds with the Al-O-X (X = Si, P, C) structural motif

The reactions of LAlH2 (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) (1) with diphenylsilanediol, phenylphosphonic acid, diphenylphosphinic acid, and pyrocatechol afford compounds with the Al-O-X (X = Si, P, C) motif of composition [LAl(μ-O)] 2Si(Ph)2 (2), [LAl(μ-O)]2PO(Ph) (3), LAl[OPO(Ph)2]2 (4), and LAl(μ-O)2(o-C 6H4) (5), respectively. Compound 2 contains the Al-O-Si-O-Al heterotrimetallic dioxide chain. Compound 3 features an Al(μ-O)]2P four-membered ring, while compound 4 exhibits a P-O-Al-O-P chain structure. Compound 5 contains the benzo-aluminum-dioxide organic-inorganic hybrid five-membered ring. Complexes 2, 3, 4, and 5 were characterized by NMR, elementary analysis, and single-crystal X-ray diffraction.