141082-00-0Relevant articles and documents
1,3-dicyclohexylimidazol-2-ylidene as a superior ligand for the nickel-catalyzed cross-couplings of aryl and benzyl methyl ethers with organoboron reagents
Tobisu, Mamoru,Yasutome, Ayaka,Kinuta, Hirotaka,Nakamura, Keisuke,Chatani, Naoto
, p. 5572 - 5575 (2015/02/19)
A new catalytic system has been developed involving the use of Ni(cod)2 in conjunction with 1,3-dicyclohexylimidazol-2-ylidene for the cross-coupling of aryl and benzyl methyl ethers with organoboron reagents. This method not only allows for the use of readily available methyl ethers as halide surrogates but also provides a functional group tolerant method for the late-stage derivatization of complex molecules.
Photochemical Reaction of Diaryliodonium Salts with Dimethylaniline
Bi, Yubai,Neckers, Douglas C.
, p. 1139 - 1142 (2007/10/02)
A solution of 4,4'-dimethyldiphenyl iodonium tettrafluoroborate and N,N-dimethylaniline in acetonitrile is irradiated by UV light to give iodotoluene, toluene, 4,4'-methylenebis(N,N-dimethylaniline), crystal violet, methyl violet. KEY WORDS: 4,4'-dimethyldiuphenyl iodonium salt; N,N-dimethylaniline; 4,4'-methylenebis(N,N-dimethylaniline); crystal violet; methyl violet.