14125-70-3Relevant articles and documents
Stereoselective synthesis of a C-glycosylic compound (a "methyl C-glycoside") through a regioselective free-radical ring-opening reaction. A single-crystal X-ray structure determination
Shanmugasundaram, Bhagavathy,Varghese, Babu,Balasubramanian, Kalpattu K
, p. 1523 - 1527 (2007/10/03)
Readily available 3,4,6-tri-O-acetyl-D-glucal was converted to 2,6-anhydro-5,7-O-benzylidene-1,3,4-trideoxy-D-arabino-hept-3-enitol, a methyl C-glycosylic compound. Cyclopropanation of 4,6-O-benzylidene-D-glucal, followed by tributylstannyl radical-mediated regioselective ring opening of the 1,2-cyclopropano sugar led to a 2,6-anhydro-1-deoxyheptose, (a "methyl C-β-D-glycoside"). The stereochemistry of the 1,2-cyclopropano sugar and the "methyl C-glycoside" were confirmed by single-crystal X-ray diffraction studies.
Free radical mediated reduction and deoxygenation of epoxides
Rajanbabu,Nugent, William A.,Beattie, Margaret S.
, p. 6408 - 6409 (2007/10/02)
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