1412737-21-3Relevant articles and documents
Syntheses and properties of two chiral multidentate carboxylate copper coordination compounds
Yu, Ying-Hui,Ren, Chang-Yue,Hou, Guang-Feng,Ye, Hantao,Gao, Jin-Sheng
, p. 4137 - 4146 (2013/02/23)
A chiral ligand, (R)-2-(4-(carboxymethoxy)phenoxy)propanoic acid, is employed as building block to construct two chiral coordination compounds, [Cu(L)(bipy)(H2O)] (1) and [Cu2(L)2(phen) 4(H2O)13] (2), by the solvent-thermal method and the volatilization method, respectively. The compounds are characterized by single-crystal X-ray diffraction (XRD), IR spectra, XRD, TGA, and circular dichroism spectra. Compound 1 is comprised of right-handed helical chains and 2 shows a separated structure, both of which extend to 3-D supramolecular framework by hydrogen bonds and π...π interactions. CD indicates both compounds retain original stereo character with strong fluorescence at room temperature.