1413934-89-0

Basic information

• Product Name: 2,4-dimethyl-1-phenyl-2-vinylpentan-1-one
• Synonyms: 2,4-dimethyl-1-phenyl-2-vinylpentan-1-one
• CAS NO: 1413934-89-0
• Molecular Weight: 216.323
• Mol File: 1413934-89-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,4-dimethyl-1-phenyl-2-vinylpentan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-dimethyl-1-phenyl-2-vinylpentan-1-one(1413934-89-0)
• EPA Substance Registry System: 2,4-dimethyl-1-phenyl-2-vinylpentan-1-one(1413934-89-0)

Safety Data

• Hazardous Substances Data: 1413934-89-0(Hazardous Substances Data)

Upstream product

• 1413934-98-1 3,5-dimethylhex-1-en-3-yl methyl carbonate 
• 99808-99-8 (R,S)-α-[(tert-butyldimethylsilyl)oxy]-α-(phenyl)acetonitrile 
• 3329-48-4 3,5-dimethyl-hex-1-en-3-ol 
• 100-52-7 benzaldehyde 

Relevant articles and documents

Rhodium-catalyzed allylic substitution with an acyl anion equivalent: Stereospecific construction of acyclic quaternary carbon stereogenic centers

A highly regio- and stereospecific rhodium-catalyzed allylic alkylation of tertiary allylic alcohol derivatives with a cyanohydrin pronucleophile is described. This direct and operationally simple protocol provides a fundamentally novel approach toward the synthesis of α-quaternary substituted ketones and circumvents many of the inherent problems associated with conventional enolate alkylation reactions. The stereospecific variant of this reaction provides the enantiomerically enriched α-quaternary substituted allylic aryl ketone, which is a particularly challenging intermediate for more conventional enolate-based strategies.