141411-64-5

Basic information

• Product Name: {((C₆H₅)3P)3PdCl}⁽¹⁺⁾*{OSO₂CF₃}^(1-)={((C₆H₅)3P)3PdCl}{OSO₂CF₃}
• Synonyms: {((C₆H₅)3P)3PdCl}⁽¹⁺⁾*{OSO₂CF₃}^(1-)={((C₆H₅)3P)3PdCl}{OSO₂CF₃}
• CAS NO: 141411-64-5
• Molecular Weight: 1077.82
• Mol File: 141411-64-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {((C₆H₅)3P)3PdCl}⁽¹⁺⁾*{OSO₂CF₃}^(1-)={((C₆H₅)3P)3PdCl}{OSO₂CF₃}(CAS DataBase Reference)
• NIST Chemistry Reference: {((C₆H₅)3P)3PdCl}⁽¹⁺⁾*{OSO₂CF₃}^(1-)={((C₆H₅)3P)3PdCl}{OSO₂CF₃}(141411-64-5)
• EPA Substance Registry System: {((C₆H₅)3P)3PdCl}⁽¹⁺⁾*{OSO₂CF₃}^(1-)={((C₆H₅)3P)3PdCl}{OSO₂CF₃}(141411-64-5)

Safety Data

• Hazardous Substances Data: 141411-64-5(Hazardous Substances Data)

Upstream product

• 13965-03-2 bis-triphenylphosphine-palladium(II) chloride 
• 2923-28-6 silver trifluoromethanesulfonate 

Relevant articles and documents

Fluoride-induced reduction of palladium(II) and platinum(II) phosphine complexes

A novel redox reaction involving fluoride and phosphine complexes of palladium(II) is reported. The scope of this reaction has been investigated using the ligands PPh3, Ph2P(CH2)nPPh2 (n = 1-4), Ph2PCH2C(CH3)2CH2PPh 2, Ph2PCH3, and P(CH2CH2CN)3; several solvents including DMSO, pyridine, acetonitrile, and THF; and either n-Bu4NF·3H2O or KF/18-crown-6 as the fluoride source. The reduction products are palladium(0) phosphine complexes for which this reaction offers a convenient synthetic route. 31P and 19F NMR spectra permitted identification of the initial oxidation products as difluorophosphoranes (R3PF2), which subsequently hydrolyzed, forming phosphine oxides if a hydrated fluoride source is used. Results implicating a fluoride-induced redox reaction in the thermal decomposition of [(Ph3P)3PdCl]BF4 to yield [Pd3Cl(PPh2)2(PPh3) 3]BF4 are also presented. Preliminary results indicate that platinum complexes also undergo this reaction, but nickel complexes yield NiF2. The X-ray parameters for Pd(dppp)2 (dppp = 1,3-bis(diphenyphosphino)propane) are: monoclinic, space group C2/c (No. 15), a = 18.396 (2) A?, b = 13.290 (1) A?, c = 20.186 (2) A?, β = 109.383 (5)°, and Z = 4.