141499-24-3

Basic information

• Product Name: Benzene, 1-(3-bromopropyl)-4-(1,1-dimethylethyl)-
• CAS NO: 141499-24-3
• Molecular Formula: C13H19Br
• Molecular Weight: 255.198
• Mol File: 141499-24-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(3-bromopropyl)-4-(1,1-dimethylethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(3-bromopropyl)-4-(1,1-dimethylethyl)-(141499-24-3)
• EPA Substance Registry System: Benzene, 1-(3-bromopropyl)-4-(1,1-dimethylethyl)-(141499-24-3)

Safety Data

• Hazardous Substances Data: 141499-24-3(Hazardous Substances Data)

Upstream product

• 3972-65-4 1-bromo-4-tert-butylbenzene 
• 109-64-8 1,3-dibromo-propane 
• 18880-00-7 1-(bromomethyl)-4-(1,1-dimethylethyl)benzene 
• 37765-76-7 2-(4-tert-butylbenzyl)diethylmalonate 
• 130872-28-5 ethyl 3-(4-(tert-butyl)phenyl)propanoate 
• 78574-08-0 3-(4-tert-butylphenyl)propan-1-ol 

Downstream Products

• 854841-82-0 [3-(4-tert-butyl-phenyl)-propyl]-malonic acid 
• 102003-61-2 5-[4-(tert.butyl)phenyl]pentanoyl chloride 
• 101100-63-4 5-(4-tertbutylphenyl)-4-hydroxypentanoic 
• 115169-81-8 1,3-dibromo-1-(4-t-butylphenyl)propane 
• 1257336-07-4 (E)-3-(1-(3-(4-tert-butylphenyl)propyl)-2-oxo-1,2-dihydropyridin-3-yl)-N-hydroxyacrylamide 

Relevant articles and documents

Air-Stable PdI Dimer Enabled Remote Functionalization: Access to Fluorinated 1,1-Diaryl Alkanes with Unprecedented Speed

While remote functionalization via chain walking has the potential to enable access to molecules via novel disconnections, such processes require relatively long reaction times and can be in need of elevated temperatures. This work features a remote arylation in less than 10 min reaction time at room temperature over a distance of up to 11 carbons. The unprecedented speed is enabled by the air-stable PdI dimer [Pd(μ-I)(PCy2tBu)]2, which in contrast to its PtBu3 counterpart does not trigger direct coupling at the initiation site, but regioconvergent and chemoselective remote functionalization to yield valuable fluorinated 1,1-diaryl alkanes. Our combined experimental and computational studies rationalize the origins of switchability, which are primarily due to differences in dispersion interactions.

Mo-Based Oxidizers as Powerful Tools for the Synthesis of Thia- and Selenaheterocycles

A highly efficient synthetic protocol for the synthesis of thia- and selenaheterocycles has been developed. By employing a MoCl5-mediated intramolecular dehydrogenative coupling reaction, a broad variety of structural motifs was isolated in yields up to 94 %. The electrophilic key transformation is tolerated by several labile moieties like halides and tertiary alkyl groups. Due to the use of disulfide or diselenide precursors, a high atom efficiency was achieved.