1415225-22-7

Basic information

• Product Name: (E)-1-methoxy-2-(3,3,4,4,5,5,6,6,6-nonafluorohex-1-en-1-yl)benzene
• Synonyms: (E)-1-methoxy-2-(3,3,4,4,5,5,6,6,6-nonafluorohex-1-en-1-yl)benzene
• CAS NO: 1415225-22-7
• Molecular Weight: 352.199
• Mol File: 1415225-22-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (E)-1-methoxy-2-(3,3,4,4,5,5,6,6,6-nonafluorohex-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-1-methoxy-2-(3,3,4,4,5,5,6,6,6-nonafluorohex-1-en-1-yl)benzene(1415225-22-7)
• EPA Substance Registry System: (E)-1-methoxy-2-(3,3,4,4,5,5,6,6,6-nonafluorohex-1-en-1-yl)benzene(1415225-22-7)

Safety Data

• Hazardous Substances Data: 1415225-22-7(Hazardous Substances Data)

Upstream product

• 19430-93-4 3,3,4,4,5,5,6,6,6-Nonafluoro-1-hexene 
• 5720-06-9 2-Methoxyphenylboronic acid 
• 529-28-2 4-iodoanisol 
• 1374104-94-5 1,3-bis(1-iodo-3,3,4,4,5,5,6,6,6-nonafluorohexan-1-yl)tetramethyldisiloxane 

Relevant articles and documents

Fluoroalkenylation of boronic acids: Via an oxidative Heck reaction

A fluoroalkenylation of boronic acids with fluoroalkyl alkenes has been developed. The Pd-catalyzed oxidative Heck coupling reaction proceeds under an oxygen atmosphere at room temperature, in the absence of a base and/or a ligand, showing excellent practicality of the process. This simple transformation is highly stereoselective to provide only E-isomers. In addition to the general approach using alkenes with functionalized fluoroalkyl reagents, this method, by transferring an aromatic system to the electron-deficient fluoroalkyl alkene, provides an efficient alternative method to yield valuable organofluorines.