1415730-50-5

Basic information

• Product Name: 1-(tert-butyl)-4-{[4-(tert-butyl)benzyl]oxy}benzene
• Synonyms: 1-(tert-butyl)-4-{[4-(tert-butyl)benzyl]oxy}benzene
• CAS NO: 1415730-50-5
• Molecular Weight: 296.453
• Mol File: 1415730-50-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(tert-butyl)-4-{[4-(tert-butyl)benzyl]oxy}benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(tert-butyl)-4-{[4-(tert-butyl)benzyl]oxy}benzene(1415730-50-5)
• EPA Substance Registry System: 1-(tert-butyl)-4-{[4-(tert-butyl)benzyl]oxy}benzene(1415730-50-5)

Safety Data

• Hazardous Substances Data: 1415730-50-5(Hazardous Substances Data)

Upstream product

• 98-54-4 para-tert-butylphenol 
• 18880-00-7 1-(bromomethyl)-4-(1,1-dimethylethyl)benzene 

Downstream Products

• 98-54-4 para-tert-butylphenol 
• 939-97-9 4-tert-Butylbenzaldehyde 
• 98-51-1 4-tert-butyltoluene 
• 71-43-2 benzene 
• 108-95-2 phenol 
• 253185-03-4 tert-butylbenzene 
• 3178-22-1 tert-butylcyclohexane 
• 75736-66-2 1-(tert-butyl)-4-methylcyclohexane 

Relevant articles and documents

Synthesis of 6 H-Benzo[ c]chromene Scaffolds from O-Benzylated Phenols through a C-H Sulfenylation/Radical Cyclization Sequence

S-Aryl dibenzothiophenium salts, obtained through a highly regioselective C-H sulfenylation of o-benzyl-protected phenols, are used as precursors of 6H-benzo[c]chromenes. The reaction starts with a photocatalytically triggered single-electron transfer to the sulfonium salt, which promotes the formation of an aryl radical via selective mesolitic cleavage of the S-Arexo bond. Mechanistic studies reveal that this initial radical species cyclizes following a kinetically favored 5-exo-trig pathway. Subsequent ring expansion, favored by rearomatization, delivers the desired tricyclic systems.