141612-30-8Relevant articles and documents
Syntheses of (+/-)-α- and (+/-)-γ-Lycorane via a Stereocontrolled Organopalladium Route
Baeckvall, Jan-E.,Andersson, Pher G.,Stone, Guy B.,Gogoll, Adolf
, p. 2988 - 2993 (1991)
Total syntheses of (+/-)-α- and (+/-)-γ-lycorane are described.The key steps in the syntheses are the stereocontrolled palladium-catalyzed intramolecular 1,4-chloroamidation of 12 to 13 and the subsequent anti-stereoselective copper-catalyzed SN/sub