14163-03-2

Basic information

• Product Name: 4-Bromo-2,2'-bipyridyl 1-oxide
• Synonyms: 4-Bromo-2,2'-bipyridyl 1-oxide;4-bromo-1-oxido-2-pyridin-2-ylpyridin-1-ium;4-bromo-2,2'-bipyridine-1-oxide
• CAS NO: 14163-03-2
• Molecular Formula: C₁₀H₇BrN₂O
• Molecular Weight: 251.07938
• Mol File: 14163-03-2.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 4-Bromo-2,2'-bipyridyl 1-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Bromo-2,2'-bipyridyl 1-oxide(14163-03-2)
• EPA Substance Registry System: 4-Bromo-2,2'-bipyridyl 1-oxide(14163-03-2)

Safety Data

• Hazardous Substances Data: 14163-03-2(Hazardous Substances Data)

Upstream product

• 14163-00-9 4-nitro-2,2'-bipyridine N-oxide 
• 33421-43-1 2,2'-bipyridyl N-oxide 
• 366-18-7 [2,2]bipyridinyl 

Downstream Products

• 1392217-95-6 3,5-bis(2,2’-bipyridin-4-ylethynyl)benzoic acid 
• 1392217-94-5 ethyl 3,5-bis(2,2’-bipyridin-4-ylethynyl)benzoate 
• 173960-50-4 C₁₆H₁₁N₃O₂ 
• 219609-65-1 2,2′-bipyridine-4-boronic acid 
• 14162-95-9 4-bromo-2,2'-bipyridyl 

Relevant articles and documents

Recyclable Transition Metal Catalysis using Bipyridine-Functionalized SBA-15 by Co-condensation of Methallylsilane with TEOS

Well-defined recyclable Pd- and Rh-bipyridyl group-impregnated SBA-15 catalysts were prepared for C?C bond coupling reaction and selective hydrogenation reactions, respectively. These SBA-15 derived ligands for the catalysts were prepared by direct and indirect co-condensation method using bipyridyl-linked methallylsilane. This indirect method, involving methoxysilane generated from methallylsilane shows higher loading efficiency of transition metal catalysts on SBA-15 than the direct use of methallylsilane.

Synthesis and Screening of Modified 6,6′-Bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydrobenzo[e][1,2,4]triazin-3-yl)-2,2′-bipyridine Ligands for Actinide and Lanthanide Separation in Nuclear Waste Treatment

Effects of chloro and bromo substitution at the 4-position of the pyridine ring of 6,6′-bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydrobenzo[e][1,2,4]triazin-3-yl)-2,2′-bipyridine (CyMe4-BTBP) have been studied with regard to the extraction of Am(III) from Eu(III) and Cm(III) from 0.1-3 M HNO3. Similarly to CyMe4-BTBP, a highly efficient (DAm > 10 at 3 M HNO3) and selective (SFAm/Eu > 100 at 3 M HNO3) extraction was observed for Cl-CyMe4-BTBP and Br-CyMe4-BTBP in 1-octanol but in the absence of a phase-transfer agent.

Synthesis of a novel dinuclear ruthenium polypyridine dye for dye-sensitized solar cells application

A new dinuclear ruthenium(II) polypyridine complex has been successfully synthesized. The new compound has been characterized by spectroscopic and electrochemical methods. Its potential application as a sensitizing dye in dye-sensitized solar cells has been checked under AM 1.5 G irradiation conditions (100 mW cm-2) and its performance was compared to that of a commercially available mononuclear analogous dye. The overall light-to-electricity conversion efficiency of the photovoltaic device sensitized by the new dinuclear dye has been found to be over 2.5 times lower than that sensitized by the commercial analogue, despite a much higher extinction coefficient of the former dye. The probable reasons for the lower photovoltaic activity are discussed.