1416982-13-2

Basic information

• Product Name: 1-(2-methoxyphenyl)-N,N,N-trimethylmethanaminium trifluoromethanesulfonate
• Synonyms: 1-(2-methoxyphenyl)-N,N,N-trimethylmethanaminium trifluoromethanesulfonate
• CAS NO: 1416982-13-2
• Molecular Weight: 329.34
• Mol File: 1416982-13-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1-(2-methoxyphenyl)-N,N,N-trimethylmethanaminium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-methoxyphenyl)-N,N,N-trimethylmethanaminium trifluoromethanesulfonate(1416982-13-2)
• EPA Substance Registry System: 1-(2-methoxyphenyl)-N,N,N-trimethylmethanaminium trifluoromethanesulfonate(1416982-13-2)

Safety Data

• Hazardous Substances Data: 1416982-13-2(Hazardous Substances Data)

Upstream product

• 6850-57-3 2-methoxybenzylamine 
• 50-00-0 formaldehyd 
• 333-27-7 methyl trifluoromethanesulfonate 
• 124-40-3 dimethyl amine 
• 58774-83-7 [(2-methoxyphenyl)methyl]dimethylamine 

Downstream Products

• 30567-87-4 2,4'-dimethoxydiphenylmethane 
• 1310048-96-4 2-(2-methoxybenzyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1225483-64-6 1-(2-methoxy-benzyl)-1H-indole 
• 124915-16-8 C₁₆H₁₈O₂Se₂ 
• 42778-12-1 1-methoxy-2-<(phenylseleno)methyl>benzene 
• 159386-46-6 (2-methoxybenzyl)diphenylphosphine oxide 

Relevant articles and documents

Synthesis of Dibenzylic Diselenides from Elemental Selenium and Benzylic Quaternary Ammonium Salts

Abstract: Substituted dibenzyl diselenides are synthesized in good yields (74–91 %) by SN2 nucleophilic substitution of benzylic trimethylammonium salts and diselenide dianion (Se2?), in situ generated from elemental selenium, under

Palladium-Catalyzed C-N Cross-Coupling of NH-Heteroarenes and Quaternary Ammonium Salts via C-N Bond Cleavage

In this paper, we extend the substrate class of Buchwald-Hartwig amination to quaternary ammonium salts. In the presence of Pd(OAc)2 and t-BuXPhos, the coupling of aryl- or arylmethyltrimethylammonium triflates with NH-heteroarenes via C-N bond cleavage affords the desired N-aryl or N-arylmethyl heteroarenes in moderate to excellent yields.

Nickel-Catalyzed Borylation of Aryl- and Benzyltrimethylammonium Salts via C-N Bond Cleavage

By developing a mild Ni-catalyzed system, a method for direct borylation of sp2 and sp3 C-N bonds has been established. The key to this hightly efficient C-N bond borylative cleavage depends on the appropriate choice of the nickel catalyst Ni(COD)2, ICy·HCl as a ligand, and the use of 2-ethoxyethanol as the cosolvent. This transformation shows good functional group compatibility and can serve as a powerful synthetic tool for gram-scale synthesis and late-stage C-N borylation of complex compounds.