1417601-05-8

Basic information

• Product Name: C₁₁₀H₁₀₈ClCuN₁₀OSZn
• Synonyms: C₁₁₀H₁₀₈ClCuN₁₀OSZn
• CAS NO: 1417601-05-8
• Molecular Weight: 1782.59
• Mol File: 1417601-05-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₁₀H₁₀₈ClCuN₁₀OSZn(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₁₀H₁₀₈ClCuN₁₀OSZn(1417601-05-8)
• EPA Substance Registry System: C₁₁₀H₁₀₈ClCuN₁₀OSZn(1417601-05-8)

Safety Data

• Hazardous Substances Data: 1417601-05-8(Hazardous Substances Data)

Upstream product

• 948863-58-9 [CuC₁₉H₈N₄(C₆H₂(CH₃)3)2(C₄N₂Cl₂SCH₃)] 
• 886359-71-3 5,10,15-tris(3,5-di-tetr-butylphenyl)-20-(4-hydroxyphenyl)porphyrinato zinc(II) 

Relevant articles and documents

Corrole-porphyrin conjugates with interchangeable metal centers

Oligoporphyrinoid materials composed of two or three tetrapyrrolic macrocycles have been synthesized by either mono-or disubstitution (S NAr) of a phenolic Zn-AB3-porphyrin on a meso-dichloropyrimidinyl-substituted Cu-AB2-corrole. Selective metallation/demetallation sequences were carried out on these mixed corrole-porphyrin conjugates to afford multichromophoric systems with variable metal centers. The absorption spectra of the free-base corrole-porphyrin systems were essentially additive, which demonstrates that only weak intercomponent interactions take place in these assemblies and therefore they can be regarded as supramolecular systems. Photophysical studies of the free-base conjugates showed that these species are highly fluorescent, with fluorescence occurring from the lowest-energy singlet state of the porphyrin subunit(s), which is (are) the lowest-energy state(s) of the assemblies. Pump-probe transient absorption spectroscopy experiments demonstrated that very efficient (>95 %) corrole-to-porphyrin singlet-singlet energy transfer takes place in these pyrimidinyl-bridged multichromophoric systems by a coulombic mechanism with rate constants on the picosecond timescale.