1418125-10-6

Basic information

• Product Name: ethyl 2-(4-methoxybenzoyl)octanoate
• Synonyms: ethyl 2-(4-methoxybenzoyl)octanoate
• CAS NO: 1418125-10-6
• Molecular Weight: 306.402
• Mol File: 1418125-10-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 2-(4-methoxybenzoyl)octanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 2-(4-methoxybenzoyl)octanoate(1418125-10-6)
• EPA Substance Registry System: ethyl 2-(4-methoxybenzoyl)octanoate(1418125-10-6)

Safety Data

• Hazardous Substances Data: 1418125-10-6(Hazardous Substances Data)

Upstream product

• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 638-45-9 1-Iodohexane 
• 2881-83-6 ethyl 4-methoxybenzoylacetate 

Downstream Products

• 67873-26-1 ethyl 2-oxooctanoate 
• 1418125-45-7 ethyl 2-hydroxy-2-(4-methoxybenzoyl)octanoate 

Relevant articles and documents

Mechanism and scope of the MnIII-initiated oxidation of β-ketocarbonyl compounds: Furan synthesis

Unless the MnIII-produced carbon-radical from β-ketocarbonyl compounds undergoes smooth intramolecular addition to alkenes, it traps molecular oxygen in the reaction medium to produce a peroxy radical, which reacts with the neighbouring carbonyl group to form 1,2-dioxetane. Thermal decomposition of 1,2-dioxetane completes the oxidation to produce α-oxo ester. This oxidation seems to be general at 50°C under aerobic conditions, and can be catalytic for MnIII in AcOH with ultrasonic irradiation. Thus, the development of a new synthetic method for diversely substituted furans has been accomplished based on a couple of the MnIII-initiated domino oxidation of β-ketocarbonyl compounds with a suitable α-allylic substitution. Copyright