141996-58-9

Basic information

• Product Name: 2,3-Furandicarboxylic acid, 2,3-dihydro-5-(4-methylphenyl)-, 2-ethyl ester
• CAS NO: 141996-58-9
• Molecular Formula: C15H16O5
• Molecular Weight: 276.289
• Mol File: 141996-58-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3-Furandicarboxylic acid, 2,3-dihydro-5-(4-methylphenyl)-, 2-ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-Furandicarboxylic acid, 2,3-dihydro-5-(4-methylphenyl)-, 2-ethyl ester(141996-58-9)
• EPA Substance Registry System: 2,3-Furandicarboxylic acid, 2,3-dihydro-5-(4-methylphenyl)-, 2-ethyl ester(141996-58-9)

Safety Data

• Hazardous Substances Data: 141996-58-9(Hazardous Substances Data)

Upstream product

• 20972-36-5 4-(p-methylphenyl)-4-oxo-2-butenoic acid 
• 1099-45-2 ethyl (triphenylphosphoranylidene)acetate 

Relevant articles and documents

ORGANOPHOSPHORUS CHEMISTRY 24. WITTIG REACTION OF β-AROYLACRYLIC- AND CINNAMIC ACIDS

The Wittig reaction of β-aroylacrylic-(2b,c) and cinnamic (4b) acids has been investigated.Depending on the experimental conditions, reaction of 2b,c with alkylidene phosphoranes (1a,b) gives the respective complex ylides 3b-e and/or the dihydrofurans (7), whereas, with benzoylmethylenetriphenylphosphorane (1c), ylide 3f or 3g is only formed.On the other hand, the reaction of 4b with 1a,b proceeded only in ethylacetate, yielding the ylides 9, accompanied by the decarboxylation of the acid.However, compound 4b did not react with 1c, under the above experimental conditions.Structural assignments are based on analytical and spectroscopic results as well as possible reaction mechanisms are annotated. Key words: β-Aroylacrylic acids; cinnamic acid; Wittig reagents, C-alkylation, O-alkylation.