14204-32-1

Basic information

• Product Name: 1H-Isoindole-1,3(2H)-dione, 2-[(4-bromophenyl)thio]-
• CAS NO: 14204-32-1
• Molecular Formula: C14H8BrNO2S
• Molecular Weight: 334.193
• Mol File: 14204-32-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: 1H-Isoindole-1,3(2H)-dione, 2-[(4-bromophenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Isoindole-1,3(2H)-dione, 2-[(4-bromophenyl)thio]-(14204-32-1)
• EPA Substance Registry System: 1H-Isoindole-1,3(2H)-dione, 2-[(4-bromophenyl)thio]-(14204-32-1)

Safety Data

• Hazardous Substances Data: 14204-32-1(Hazardous Substances Data)

Upstream product

• 54974-07-1 phthalimidesulfenyl chloride 
• 106-37-6 1.4-dibromobenzene 
• 7764-30-9 2,2'-disulfanediylbis(isoindoline-1,3-dione) 
• 136918-14-4 phthalimide 
• 3481-09-2 N-chlorophthalimide 
• 106-53-6 para-bromobenzenethiol 

Downstream Products

• 1293490-30-8 2-(diethoxyphosphinyl)-2-(4-bromophenylthio)-1-oxo-1,2,3,4-tetrahydronaphthalene 
• 1330745-76-0 1-(4-bromophenyl)-2-(4-methoxyphenyl)disulfane 
• 92025-54-2 4-bromophenyl phenyl disulfide 
• 5335-84-2 bis(4-bromophenyl)disulfide 
• 110121-12-5 C₁₂H₈BrClS₂ 
• 40897-58-3 1-(4-bromophenyl)-2-(4-nitrophenyl)disulfane 
• 498-83-9 4-bromobenzenesulfonyl fluoride 
• 1062609-73-7 4-bromophenyltetetrafluoro-λ⁶-sulfanyl chloride 

Relevant articles and documents

Electrochemical Direct Thiolation of Lactams with Mercaptans: An Efficient Access to N-Acylsulfenamides

An efficient and eco-friendly electrochemical methodology for the oxidative cross coupling hydrogen evolution (CCHE) reactions of lactams with thiols is presented. Various electron deficient N-acylsulfenamides are smoothly produced in modest to excellent yields without using any external oxidant. Elementary mechanistic insight supports a possible free radical process and hydrogen is the only side product. This approach provides a safe, convenient, and economical preparation of synthetically important N-thiophthalimides on a gram scale.

Copper-Catalyzed Electrophilic Thiolation of Organozinc Halides by Using N-Thiophthalimides Leading to Polyfunctional Thioethers

(Hetero)aryl, benzylic, and alkyl zinc halides were thiolated with N-thiophthalimides at 25 °C within 1 h in the presence of 5–10 % Cu(OAc)2?H2O to furnish the corresponding polyfunctionalized thioethers in good yields. This electrop

A facile synthesis of 3,4-dimercaptofurans via sulfenylation of (E)-β-chlorovinyl ketones and 1,2-sulfur migration

The one-pot sulfenylation of (E)-β-chlorovinyl ketones was investigated under soft α-vinyl enolization conditions. Modulating the nature of nucleophilic species using a “hard” base the regioselective formation of α,γ-dithio-allenyl ketones has been achieved, where the thermodynamic control was mimicked by the presence of Et3N·HCl. The sulfenylated products, α,γ-dithio-allenyl and α,α-dithio-propargyl ketones, smoothly underwent cycloisomerization to 3,4-dimercaptofurans via a novel 1,2-sulfur migration in excellent yields.