142048-19-9

Basic information

• Product Name: Benzene, 1-methyl-4-[(1-methylene-2-propenyl)sulfinyl]-, (R)-
• CAS NO: 142048-19-9
• Molecular Formula: C11H12OS
• Molecular Weight: 192.282
• Mol File: 142048-19-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-4-[(1-methylene-2-propenyl)sulfinyl]-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-4-[(1-methylene-2-propenyl)sulfinyl]-, (R)-(142048-19-9)
• EPA Substance Registry System: Benzene, 1-methyl-4-[(1-methylene-2-propenyl)sulfinyl]-, (R)-(142048-19-9)

Safety Data

• Hazardous Substances Data: 142048-19-9(Hazardous Substances Data)

Upstream product

• 142048-22-4 2-ethoxyethyl p-tolyl (R_S)-sulfoxide 
• 235100-20-6 (S)_S-3-p-tolylsulfinyl-3-buten-2-ol 
• 195064-64-3 Methanesulfonic acid 2-iodo-2-((S)-toluene-4-sulfinyl)-ethyl ester 
• 195064-63-2 2-Iodo-2-((S)-toluene-4-sulfinyl)-ethanol 
• 99930-83-3 (R)-ethynyl-p-tolyl-sulfoxide 
• 54828-68-1 (R)-p-tolyl vinyl sulfoxide 
• 7486-35-3 tri-n-butyl(vinyl)tin 
• 167690-68-8 (+)-1-iodo-1-[(S)-p-tolylsulfinyl]ethene 
• 142079-86-5 Methanesulfonic acid 1-methyl-2-((S)-toluene-4-sulfinyl)-allyl ester 

Relevant articles and documents

Synthesis and diastereoselective complexation of enantiopure sulfinyl dienes: The preparation of sulfinyl iron(0) dienes

The preparation of a diverse array of enantiomerically pure 1- and 2- sulfinyl dienes has been achieved via Stille coupling of halovinyl sulfoxides and vinyl stannanes, hydrogenation of 1-sulfinyl-1-en-3-ynes, or vinylcupration of 1-sulfinyl alkynes. Form

An easy synthesis of chiral sulfinyl allylic bromides and their use in the preparation of (R)(S)- and (S)(S)-2-p-tolylsulfinyl-1,3-alkadienes

Condensation of (R)-vinyl-o-tolylsulfoxide anion on carbonyl compounds led directly to chiral allylic sulfinylalcohols 1. By treatment with NBS/Me2S, these alcohols 1 were converted into the rearranged primary allylic bromides 2 via SN2/s