142068-28-8Relevant articles and documents
Ni(II) and Co(II) complexes of an asymmetrical aroylhydrazone: Synthesis, molecular structures, DNA binding, protein interaction, radical scavenging and cytotoxic activity
Li, Yueqin,Yang, Zhiwei,Zhou, Minya,Li, Yun,He, Jing,Wang, Xuehong,Lin, Zhengfeng
, p. 41527 - 41539 (2017)
Two new nickel(ii) and cobalt(ii) benzhydrazone complexes having the general formula [ML2phen·3CH3OH] (where M = Ni and Co, L = 2-acetonaphthonebenzoylhydrazone, phen = 1,10-phenanthroline) have been synthesized via the reaction of N
Enantioselective Allylation of Ketone-Derived Benzoylhydrazones: Practical Synthesis of Tertiary Carbinamines
Berger, Richard,Duff, Keiko,Leighton, James L.
, p. 5686 - 5687 (2007/10/03)
A highly practical method for the enantioselective allylation of ketone-derived benzoylhydrazones has been developed. The previously reported strained silacycle reagent 1 reacts with a wide variety of benzoylhydrazones to give the hydrazide products with
Catalytic asymmetric reductive amination of ketones via highly enantioselective hydrogenation of the C=N double bond
Burk, Mark J.,Martinez, Jose P.,Feaster, John E.,Cosford, Nick
, p. 4399 - 4428 (2007/10/02)
We describe a convenient, chemoselective asymmetric reductive amination procedure for the conversion of ketones to chiral hydrazines and amines. The key step in the three-step process is enantioselective DuPHOS-Rh-catalyzed hydrogenation of the C=N double bond of N-acylhydrazones. Detailed optimization studies revealed the effect of solvent, temperature, and the N- acyl group on the enantioselectivity and catalytic efficiency of the reaction. The reduction products, N-acylhydrazines, were converted to hydrazines or amines through hydrolysis or treatment with samarium(II) iodide, respectively.
