142231-02-5

Basic information

• Product Name: 1H-Pyrrole, 2,5-dimethyl-1-[2-(phenylmethyl)phenyl]-
• CAS NO: 142231-02-5
• Molecular Formula: C19H19N
• Molecular Weight: 261.367
• Mol File: 142231-02-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1H-Pyrrole, 2,5-dimethyl-1-[2-(phenylmethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Pyrrole, 2,5-dimethyl-1-[2-(phenylmethyl)phenyl]-(142231-02-5)
• EPA Substance Registry System: 1H-Pyrrole, 2,5-dimethyl-1-[2-(phenylmethyl)phenyl]-(142231-02-5)

Safety Data

• Hazardous Substances Data: 142231-02-5(Hazardous Substances Data)

Upstream product

• 28059-64-5 2-benzylaniline 
• 110-13-4 2,5-hexanedione 

Relevant articles and documents

Enantiomers and Barriers to Racemization of Sterically Hindered N-Aryl- and N-Heteroarylpyrroles

The N-aryl- and N-heteroaryl-2,5-dimethylpyrrole-3-carbaldehydes 2-8 have been synthesized by condensation of hexane-2,5-dione with the appropriate amine and subsequent Vilsmeier-Haack formylation of the pyrrole ring.Diastereomeric association complexes of the racemic pyrrole 8 were studied by pmr chemical shifts and the aplittings induced by (+)-1-(9-anthryl)-2,2,2-trifluoroethanol.Enrichment of the enantiomers M and P of 2 and 6 was achieved by liquid chromatography on triacetylcellulose.The barrier to partial rotation about the C-N bond in 6 was determined by thermal racemization and its lower limits in 2 and 8 were estimated.