1422450-70-1Relevant articles and documents
Threefold cross-linked polystyrene-triphenylphosphane hybrids: Mono-P-ligating behavior and catalytic applications for aryl chloride cross-coupling and C(sp3)-H borylation
Iwai, Tomohiro,Harada, Tomoya,Hara, Kenji,Sawamura, Masaya
supporting information, p. 12322 - 12326 (2013/12/04)
Covalently bound polystyrene-phosphane hybrids were prepared by a method based on radical emulsion polymerization of styrenes in the presence of a tris(p-vinylphenyl)phosphane cross-linker. These hybrids favor mono-P-ligation to transition-metal complexes and are useful for challenging catalysis, such as Pd-catalyzed C-C/C-N couplings with unactivated chloroarenes and Ir- or Rh-catalyzed C(sp3)-H borylations. Copyright