1422529-12-1

Basic information

• Product Name: C₂₈H₂₈Si
• CAS NO: 1422529-12-1
• Molecular Weight: 392.616
• Mol File: 1422529-12-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₈H₂₈Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₈H₂₈Si(1422529-12-1)
• EPA Substance Registry System: C₂₈H₂₈Si(1422529-12-1)

Safety Data

• Hazardous Substances Data: 1422529-12-1(Hazardous Substances Data)

Upstream product

• 712278-29-0 1-{2-[2-(4-methylphenyl)-1-ethynyl]phenyl}-3-(trimethylsilyl)-2-propyn-1-ol 
• 189008-33-1 2-[2-(4-methylphenyl)ethynyl]benzaldehyde 
• 766-97-2 4-n-methylphenylacetylene 
• 1429218-38-1 trimethyl(1-m-tolyl-3-(2-(p-tolylethynyl)phenyl)propa-1,2-dienyl)silane 
• 1422529-03-0 1-(2-(4-tolylethynyl)phenyl)-3-(trimethylsilyl)prop-2-ynyl acetate 

Relevant articles and documents

Nonstatistical dynamic effects in the thermal C2-C6 Diels-Alder cyclization of enyne-allenes

The Diels-Alder (DA) reaction channel of the thermal C2-C 6 (Schmittel) cyclization of enyne-allenes is studied computationally and experimentally evaluating the influence of temperature on product ratios. Remote substituents at the alkyne terminus influence the mechanism of the C 2-C6/DA cyclization steering it either to a stepwise or a concerted course. Temperature independent product ratios, selectivity of product formation, and computational results obtained at (U)BLYP/6-31G(d) level unveil a mechanism that is strongly controlled by nonstatistical dynamics.