1424351-60-9Relevant articles and documents
A microporous metal-organic framework of a rare sty topology for high CH4 storage at room temperature
Duan, Xing,Yu, Jiancan,Cai, Jianfeng,He, Yabing,Wu, Chuande,Zhou, Wei,Yildirim, Taner,Zhang, Zhangjing,Xiang, Shengchang,O'Keeffe, Michael,Chen, Banglin,Qian, Guodong
, p. 2043 - 2045 (2013)
A rare sty type microporous metal-organic framework, Cu2(FDDI) (ZJU-25; H4FDDI = tetramethyl 5,5′-(9H-fluorene-2,7-diyl) diisophthalate acid), was solvothermally synthesized and structurally characterized. With open metal sites and suitable pore space for their interactions with methane molecules, ZJU-25a exhibits absolute methane storage of 180 cm3(STP) cm-3 at room temperature and 35 bar, enabling it to be one of the very few porous MOFs whose methane storage capacities have met and/or approached the DOE target of 180 cm3(STP) cm-3 for material-based methane storage. The Royal Society of Chemistry 2013.