1424999-26-7

Basic information

• Product Name: 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane
• Synonyms: 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane
• CAS NO: 1424999-26-7
• Molecular Weight: 308.206
• Mol File: 1424999-26-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane(1424999-26-7)
• EPA Substance Registry System: 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)prop-1-en-2-yl)-1,3,2-dioxaborolane(1424999-26-7)

Safety Data

• Hazardous Substances Data: 1424999-26-7(Hazardous Substances Data)

Upstream product

• 5651-88-7 phenyl propargyl sulfide 
• 1424999-68-7 trimethyl(1-(phenylsulfonyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl)silane 
• 1950-77-2 benzenesulfonyl iodide 
• 98-11-3 benzenesulfonic acid 
• 1120-90-7 3-iodopyridine 
• 1424999-30-3 2-(2-iodo-1-(phenylsulfonyl)propan-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 2525-40-8 prop-2-ynylsulfonylbenzene 
• 73183-34-3 bis(pinacol)diborane 

Downstream Products

• 251928-75-3 2-(3-phenylprop-1-en-2-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1424999-32-5 4,4,5,5-tetramethyl-2-(5-(phenylsulfonyl)cyclopent-1-en-1-yl)-1,3,2-dioxaborolane 
• 1424999-40-5 potassium (5-(phenylsulfonyl)cyclopent-1-en-1-yl)trifluoroborate 
• 1424999-38-1 3-(5-(phenylsulfonyl)cyclopent-1-en-1-yl)pyridine 
• 1424999-36-9 4,4,5,5-tetramethyl-2-(2-(3-phenylpropyl)-5-(phenylsulfonyl)cyclopent-1-en-1-yl)-1,3,2-dioxaborolane 
• 515-42-4 sodium phenylsulfonate 
• 1424999-28-9 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)but-1-en-2-yl)-1,3,2-dioxaborolane 
• 1424999-42-7 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)pent-1-en-2-yl)-1,3,2-dioxaborolane 
• 1424999-44-9 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)hex-1-en-2-yl)-1,3,2-dioxaborolane 
• 1424999-46-1 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)hept-1-en-2-yl)-1,3,2-dioxaborolane 
• 1424999-48-3 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)non-1-en-2-yl)-1,3,2-dioxaborolane 
• 1424999-50-7 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)hexa-1,5-dien-2-yl)-1,3,2-dioxaborolane 
• 1424999-52-9 4,4,5,5-tetramethyl-2-(4-phenyl-3-(phenylsulfonyl)but-1-en-2-yl)-1,3,2-dioxaborolane 
• 1424999-54-1 4,4,5,5-tetramethyl-2-(3-(phenylsulfonyl)hepta-1,6-dien-2-yl)-1,3,2-dioxaborolane 

Relevant articles and documents

Radical isomerization of borylated allylic sulfones

We report a preliminary study of the radical isomerization of borylated allylic sulfones to their more thermodynamically stable isomers. This reaction is important as it provides access to structurally unique vinyl boronates not easily accessible by other

Formal regiocontrolled hydroboration of unbiased internal alkynes via borylation/allylic alkylation of terminal alkynes

In accessing trisubstituted vinyl boronates from terminal alkynes, a propargyl directing (2-pyridyl)sulfonyl group allows terminal alkynes to undergo Cu-catalyzed B2(pin)2-borylation and subsequent Cu-catalyzed allylic alkylation wit