1425-09-8Relevant articles and documents
Efficient method for inversion of secondary alcohols by reaction of chloromethanesulfonates with cesium acetate
Shimizu, Takeshi,Hiranuma, Sayoko,Nakata, Tadashi
, p. 6145 - 6148 (2007/10/03)
Inversion of a variety of secondary alcohols using the (chloromethylsulfonyl)oxy group as a favorable leaving group with cesium acetate in the presence of 18-crown-6 has been performed to give the inverted acetates in high yields.