1425088-81-8Relevant articles and documents
Synthesis and root growth activity of some new acetylhydrazinecarbothioamides and 1,2,4-triazoles substituted with the 5H-dibenzo[a,d][7]annulene moiety
Socea, Laura I.,Apostol, Theodora V.,SSaramet, Gabriel,Barbuceanu, Stefania F.,Draghici, Constantin,Dinu, Mihaela
, p. 1541 - 1549 (2013/03/14)
New hydrazinecarbothioamides 5a-d bearing 5H-dibenzo[a,d][7]annulene moiety were synthesized using classical procedures. 1H-NMR analysis indicated the existence of two conformational isomers, a major axial (about 75 %) and a minor equatorial one (25 %), which are interconvertible by middle ring inversion. Cyclization of compounds 5a-d in NaOH solution produced the corresponding 4H-1,2,4-triazole-3-thiols (6a-d) that proved to be pure axial isomers. All the new compounds were extensively characterized by elemental analysis, IR, UV, 1H-NMR and 13C-NMR spectroscopy and were biologically investigated using phytobiological tests. Copyright