142592-73-2

Basic information

• Product Name: 1,4-Hexanediol, 6-(phenylmethoxy)-, (S)-
• CAS NO: 142592-73-2
• Molecular Formula: C13H20O3
• Molecular Weight: 224.3
• Mol File: 142592-73-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,4-Hexanediol, 6-(phenylmethoxy)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-Hexanediol, 6-(phenylmethoxy)-, (S)-(142592-73-2)
• EPA Substance Registry System: 1,4-Hexanediol, 6-(phenylmethoxy)-, (S)-(142592-73-2)

Safety Data

• Hazardous Substances Data: 142592-73-2(Hazardous Substances Data)

Upstream product

• 115114-87-9 (2R)-2-(2-benzyloxyethyl)oxirane 
• 69985-32-6 (R)-4-phenylmethoxy-1,2-butanediol 
• 159517-86-9 (R)-(+)-4-(2-benzyloxyethyl)-2,2-dimethyl-1,3-dioxolane 
• 91285-62-0 (S)-1-(benzyloxy)-3-hydroxyhex-5-ene 

Downstream Products

• 142592-60-7 <2S(S),3R,6S,8S>-N-<6-hydroxy-2-(methoxycarbonyl)-3-<<2-(trimethylsilyl)ethoxy>methoxy>phenyl>-2-<1-<<1-<<2-(trimethylsilyl)ethoxy>methoxy>-2-pyrrolidyl>carbonyl>ethyl>-1,7-dioxaspiro<5.5>undecane-8-acetamide 
• 142592-58-3 <2S(2S,3R,6S,8S)>-2-<3-methyl-8-<2-(benzyloxy)ethyl>-1,7-dioxaspiro<5.5>undecan-2-yl>-1-<1-<<2-(trimethylsilyl)ethoxy>methoxy>-2-pyrrolidyl>-1-propanone 
• 142592-76-5 (βR,2S,3R,6S,8S)-2-<α-(tert-butyldiphenylsilyloxy)ethyl>-8-<2-(benzyloxy)ethyl>-β,3-dimethyl-1,7-dioxaspiro<5.5>undecane 
• 99623-84-4 Routiennocin 
• 144604-71-7 (βR,2S,3R,6S,8S)-2-[α-(tert-butyldiphenylsilyloxy)ethyl]-β,3-dimethyl-1,7-dioxaspiro[5.5]undecane-8-ethanol 
• 142592-57-2 (αR,2S,3R,6S,8S)-8-<2-(benzyloxy)ethyl>-α,3-dimethyl-1,7-dioxaspiro<5.5>undecane-2-ethanal 
• 142592-56-1 (βR,2S,3R,6S,8S)-8-<2-(benzyloxy)ethyl>-β,3-dimethyl-1,7-dioxaspiro<5.5>undecane-2-ethanol 
• 142592-74-3 (4S)-4-<2-(benzyloxy)ethyl>-2,2-dimethyl-1,3-dioxepane 

Relevant articles and documents

Intramolecular thermal stepwise [2 + 2] cycloadditions: Investigation of a stereoselective synthesis of [n.2.0]-bicyclolactones

Fused cyclobutanes are found in a range of natural products and formation of these motifs in a straightforward and easy manner represents an interesting synthetic challenge. To this end we investigated an intramolecular variant of the thermal enamine [2 + 2] cyclisation, developing a diastereoselective intramolecular enamine [2 + 2] cyclisation furnishing δ lactone and lactam fused cyclobutenes in good yield and excellent diastereoselectivity.